Oxygen isotopic compositions of chondrules: Implications for evolution of oxygen isotopic reservoirs in the inner solar nebula

We review the oxygen isotopic compositions of minerals in chondrules and compound objects composed of a chondrule and a refractory inclusion, and bulk oxygen isotopic compositions of chondrules in unequilibrated ordinary, carbonaceous, enstatite, and Kakangari-like chondrites, focusing on data acquired using secondary ion mass-spectrometry and laser fluorination coupled with mass-spectrometry over the last decade. Most ferromagnesian chondrules from primitive (unmetamorphosed) chondrites are isotopically uniform (within 3–4‰ in Δ¹⁷O) and depleted in ¹⁶O (Δ¹⁷O>−7‰) relative to amoeboid olivine aggregates (AOAs) and most calcium–aluminum-rich inclusions (CAIs) (Δ¹⁷O<−20‰), suggesting that these classes of objects formed in isotopically distinct gaseous reservoirs, ¹⁶O-poor and ¹⁶O-rich, respectively. Chondrules uniformly enriched in ¹⁶O (Δ¹⁷O<−15‰) are exceptionally rare and have been reported only in CH chondrites. Oxygen isotopic heterogeneity in chondrules is mainly due to the presence of relict grains. These appear to consist of chondrules of earlier generations and rare refractory inclusions; with rare exceptions, the relict grains are ¹⁶O-enriched relative to chondrule phenocrysts and mesostasis. Within a chondrite group, the magnesium-rich (Type I) chondrules tend to be ¹⁶O-enriched relative to the ferrous (Type II) chondrules. Aluminum-rich chondrules in ordinary, enstatite, CR, and CV chondrites are generally ¹⁶O-enriched relative to ferromagnesian chondrules. No systematic differences in oxygen isotopic compositions have been found among these chondrule types in CB chondrites. Aluminum-rich chondrules in carbonaceous chondrites often contain relict refractory inclusions. Aluminum-rich chondrules with relict CAIs have heterogeneous oxygen isotopic compositions (Δ¹⁷O ranges from −20‰ to 0‰). Aluminum-rich chondrules without relict CAIs are isotopically uniform and have oxygen isotopic compositions similar to, or approaching, those of ferromagnesian chondrules. Phenocrysts and mesostases of the CAI-bearing chondrules show no clear evidence for ¹⁶O-enrichment compared to the CAI-free chondrules. Spinel, hibonite, and forsterite of the relict refractory inclusions largely retained their original oxygen isotopic compositions. In contrast, plagioclase and melilite of the relict CAIs experienced melting and ¹⁶O-depletion to various degrees, probably due to isotopic exchange with an ¹⁶O-poor nebular gas. Several igneous CAIs experienced isotopic exchange with an ¹⁶O-poor nebular gas during late-stage remelting in the chondrule-forming region. On a three-isotope diagram, bulk oxygen isotopic compositions of most chondrules in ordinary, enstatite, and carbonaceous chondrites plot above, along, and below the terrestrial fractionation line, respectively. Bulk oxygen isotopic compositions of chondrules in altered and/or metamorphosed chondrites show evidence for mass-dependent fractionation, reflecting either interaction with a gaseous/fluid reservoir on parent asteroids or open-system thermal metamorphism. Bulk oxygen isotopic compositions of chondrules and oxygen isotopic compositions of individual minerals in chondrules and refractory inclusions from primitive chondrites plot along a common line of slope of 1, suggesting that only two major reservoirs (gas and solids) are needed to explain the observed variations. However, there is no requirement that each had a permanently fixed isotopic composition. The absolute (²⁰⁷Pb–²⁰⁶Pb) and relative (²⁷Al–²⁶Mg) chronologies of CAIs and chondrules and the differences in oxygen isotopic compositions of most chondrules (¹⁶O-poor) and most refractory inclusions (¹⁶O-rich) can be interpreted in terms of isotopic self-shielding during UV photolysis of CO in the initially ¹⁶O-rich (Δ¹⁷O−25‰) parent molecular cloud or protoplanetary disk. According to these models, the UV photolysis preferentially dissociates C¹⁷O and C¹⁸O in the parent molecular cloud and in the peripheral zones of the protoplanetary disk. If this process occurs in the stability field of water ice, the released atomic ¹⁷O and ¹⁸O are incorporated into water ice, while the residual CO gas becomes enriched in ¹⁶O. During the earliest stages of evolution of the protoplanetary disk, the inner solar nebula had a solar H₂O/CO ratio and was ¹⁶O-rich. During this time, AOAs and the ¹⁶O-rich CAIs and chondrules formed. Subsequently, the inner solar nebula became H₂O- and ¹⁶O-depleted, because ice-rich dust particles, which were depleted in ¹⁶O, agglomerated outside the snowline (5 AU), drifted rapidly towards the Sun and evaporated. During this time, which may have lasted for 3 Myr, most chondrules and the ¹⁶O-depleted igneous CAIs formed. We infer that most chondrules formed from isotopically heterogeneous, but ¹⁶O-depleted precursors, and experienced isotopic exchange with an ¹⁶O-poor nebular gas during melting. Although the relative roles of the chondrule precursor materials and gas–melt isotopic exchange in establishing oxygen isotopic compositions of chondrules have not been quantified yet, mineralogical, chemical, and isotopic evidence indicate that Type I chondrules may have formed in chemical and isotopic equilibrium with nebular gas of variable isotopic composition. Whether these variations were spatial or temporal are not known yet.     

Transport of terrestrial organic matter in the Ogooué deep sea turbidite system (Gabon)

In order to define the nature and distribution of the organic matter (OM) preserved in the modern Ogooué deep sea turbidite system (Gabon), bulk geochemical techniques (Rock-Eval pyrolysis, elemental and isotopic analyses) and palynofacies were applied to three piston cores collected in the Cape Lopez Canyon and lobe and on the continental slope, north of the canyon.The hemipelagic sedimentation in the study area is characterized by high accumulations of well-preserved OM (∼2-3 wt. TOC %). Bulk geochemical and palynofacies analysis indicate both a marine and terrestrial origin of the OM. Contribution of the marine source is higher on the slope than in the canyon and lobe.OM accumulation in turbidites is strongly controlled by the combined influence of the Cape Lopez Canyon and littoral drift. In the canyon and lobe, turbidites show generally low TOC content (0.5 wt. %) and OM is oxidized. The origin of the OM is interpreted as both marine and terrestrial, with a higher contribution of continental source versus marine source. The low TOC contents are due to the large siliciclastic fraction transported by the littoral drift and diverted in the Cape Lopez Canyon during high energy processes (e.g. storms) which tend to dilute the OM in the turbidites. Transport by long-shore currents and/or turbiditic flows leads to oxidation of the OM.On the continental slope located north of the Cape Lopez Canyon, large amounts of OM are deposited in turbidites (up to 14 wt. %). The OM is predominantly derived from terrestrial land plants and has not been subjected to intense oxidation. These deposits are characterized by high hydrocarbon potential (up to 27 kg HC/t rock), indicating a good potential as gas-prone source rock. Because Cape Lopez Canyon captures a significant part of the sediment transported by the littoral drift, the siliciclastic sedimentary flux is reduced north of the canyon; OM is thus concentrated in the turbidites. Variation in TOC content within turbidite laminae can be explained by the burst and sweep deposition process affecting the boundary layer of the turbulent flow.This study confirms that gravity flows play a preponderant role in the accumulation and preservation of OM in deep water and that deep sea turbidite systems could be regarded as an environment where organic sedimentation occurs.     

Thermohaline variability and Antarctic bottom water formation at the Ross Sea shelf break

We use hydrological and current meter data collected in the Ross Sea, Antarctica between 1995 and 2006 to describe the spatial and temporal variability of water masses involved in the production of Antarctic Bottom Water (AABW). Data were collected in two regions of known outflows of dense shelf water in this region; the Drygalski Trough (DT) and the Glomar-Challenger Trough (GCT). Dense shelf water just inshore of the shelf break is dominated by High Salinity Shelf Water (HSSW) in the DT and Ice Shelf Water (ISW) in the GCT. The HSSW in the northern DT freshened by ∼0.06 in 11 y, while the ISW in the northern GCT freshened by ∼0.04 in 8 y and warmed by ∼0.04 °C in 11 y, dominated by a rapid warming during austral summer 2001/02. The Antarctic Slope Front separating the warm Circumpolar Deep Water (CDW) from the shelf waters is more stable near GCT than near DT, with CDW and mixing products being found on the outer DT shelf but not on the outer GCT shelf. The different source waters and mixing processes at the two sites lead to production of AABW with different thermohaline characteristics in the central and western Ross Sea. Multi-year time series of hydrography and currents at long-term moorings within 100 km of the shelf break in both troughs confirm the interannual signals in the dense shelf water and reveal the seasonal cycle of water mass properties. Near the DT the HSSW salinities experienced maxima in March/April and minima in September/October. The ISW in the GCT is warmest in March/April and coolest between August and October. Mooring data also demonstrate significant high-frequency variability associated with tides and other processes. Wavelet analysis of near-bottom moored sensors sampling the dense water cascade over the continental slope west of the GCT shows intermittent energetic pulses of cold, dense water with periods from ∼32 h to ∼5 days.     

The lherzolitic shergottite Grove Mountains 99027: Rare earth element geochemistry

Abstract— We report here on an ion probe study of rare earth element (REE) geochemistry in the lherzolitic shergottite Grove Mountains (GRV) 99027. This meteorite shows almost identical mineralogy, petrology, and REE geochemistry to those of the lherzolitic shergottites Allan Hills (ALH) A77005, Lewis Cliff (LEW) 88516, and Yamato (Y‐) 793605. REE concentrations in olivine, pyroxenes, maskelynite, merrillite, and melt glass are basically comparable to previous data obtained from ALH A77005, LEW 88516, and Y‐793605. Olivine is the dominant phase in this meteorite. It is commonly enclosed by large (up to several mm) pigeonite oikocrysts. Non‐poikilitic areas consist of larger olivine grains (?mm), pigeonite, augite, and maskelynite. Minor merrillite (up to 150 μm in size) is widespread in non‐poikilitic regions, occurring interstitially between olivine and pyroxene grains. It is the main REE carrier in GRV 99027 and has relatively higher REEs (200–1000 × CI) than that of other lherzolitic shergottites. A REE budget calculation for GRV 99027 yields a whole rock REE pattern very similar to that of other lherzolites. It is characterized by the distinctive light REE depletion and a smooth increase from light REEs to heavy REEs. REE microdistributions in GRV 99027 strongly support the idea that all lherzolitic shergottites formed by identical igneous processes, probably from the same magma chamber on Mars. Despite many similarities in mineralogy, petrography, and trace element geochemistry, subtle differences exist between GRV 99027 and other lherzolitic shergottites. GRV 99027 has relatively uniform mineral compositions (both major elements and REEs), implying that it suffered a higher degree of sub‐solidus equilibration than the other three lherzolites. It is notable that GRV 99027 has experienced terrestrial weathering in the Antarctic environment, as its olivine and pyroxenes commonly display a light REE enrichment and a negative Ce anomaly. Caution needs to be taken in future chronological studies.     

Cenozoic evolution of the central Myanmar drainage system: insights from sediment provenance in the Minbu Sub‐Basin

Located at the southern edge of the eastern Himalayan syntaxis, the Central Myanmar Basin (CMB) is divided into several Tertiary sub‐basins that have been almost continuously filled since the Indo‐Asia collision. They are currently drained by the Irrawaddy River, which flows down the eastern Tibetan Plateau and the Sino‐Burman Ranges. Tracing sediment provenance from the CMB is thus critical for reconstructing the past denudation of the Himalayan‐Tibetan orogen; it is especially relevant since a popular drainage scenario involves the capture of the Tsangpo drainage system in Tibet by a precursor to the Irrawaddy River. Here, we document the provenance of sediment samples from the Minbu Sub‐Basin at the southern edge of the CMB, which is traversed by the modern stream of the Irrawaddy River. Samples ranging in age from middle Eocene to Pleistocene were investigated using Nd isotopes, trace element geochemistry and sandstone modal compositions. Our data provide no evidence of a dramatic provenance shift; however, sandstone petrography, trace element ratios and isotopic values display long‐term trends indicating a gradual decrease of the volcanic input and its replacement by a dominant supply from the Burmese basement. These trends are interpreted to reflect the progressive denudation of the Andean‐type volcanic arc that extended onto the Burmese margin, along the flank of the modern Sino‐Burman Ranges, where most of the post‐collisional deformation of central Myanmar is located. Though our results do not exclude an ephemeral or diluted contribution from a past Tsangpo‐Irrawaddy connection, sedimentation rates suggest that this hypothesis is unlikely before the development of a stable Tsangpo‐Brahmaputra River in the Miocene. These results thus suggest that the central Myanmar drainage basin has remained restricted to the Sino‐Burman Ranges since the beginning of the India‐Asia collision.     

Hydro-acoustic remote sensing of benthic biological communities on the shallow South East Australian continental shelf

Information regarding the composition and extent of benthic habitats on the South East Australian continental shelf is limited. In this habitat mapping study, multibeam echosounder (MBES) data are integrated with precisely geo-referenced video ground-truth data to quantify benthic biotic communities at Cape Nelson, Victoria, Australia. Using an automated decision tree classification approach, 5 representative biotic groups defined from video analysis were related to hydro-acoustically derived variables in the Cape Nelson survey area. Using a combination of multibeam bathymetry, backscatter and derivative products produced highest overall accuracy (87%) and kappa statistic (0.83). This study demonstrates that decision tree classifiers are capable of integrating variable data types for mapping distributions of benthic biological assemblages, which are important in maintaining biodiversity and other system services in the marine environment.     

Marine scavenging: Trace metal adsorption by interfacial sediment from MANOP Site H

The adsorption of thirteen trace metals from seawater was studied on interfacial sediment from MANOP site H. The adsorption data indicate a long (~20 day) equilibration time for most metals, an increase in adsorption with an increase in pH and particle concentration, a dependence of adsorption on total metal concentration at high adsorption densities, and a lack of correlation between metal binding ability and metal hydrolysis in solution.Apparent equilibrium binding constants normalized to the total number of available sites on the solid were determined for metal binding with the interfacial sediment. The binding constants indicate that the affinity sequence for metal interactions with the interfacial sediment is: Pb > Fe > Sn ? Co≈ Mn > Cu > Be > Sc ? Zn > Ni > Cd ? Ba > Cs at pH 7.82 in seawater.A comparison of the binding constants for suspended particles, interfacial sediment, and surface sediment indicate that the composition of particles influences the binding ability of the particles. Biogenic particles tend to bind most metals more strongly than lithogenic or authigenic particles.Based on limited data, there is a strong positive correlation between the measured binding constants and the observed partitioning of metals between sediment and seawater.     

The longevity of subcontinental lithospheric mantle beneath Jiangsu-Anhui Region ——The Os isotope model age of mantle-derived peridotite xenoliths

The basalt-borne peridotite xenoliths from Jiangsu-Anhui provinces were analyzed for whole rock Os isotopic compositions in two laboratories of USTC, China and CRPG, France, respectively. The 187Os/188Os ratio of the sample set ranges from 0.119 to 0.129 (25 samples, USTC)and from 0.117 to 0.131 (17 samples, CRPG). The Os isotopic compositions of most samples are less than 0.129 and depleted relatively to the primitive mantle, showing a good correlation with the major element compositions. With the 187Os/188Os-Al2O3 alumichron, the samples yield a model age of 2.5 ± 0.1 Ga (data of USTC) and 1.9 ± 0.1 Ga (data of CRPG), late Archean to early Proterozoic, The two samples with the lowest 187Os/188Os ratio (0.119 and 0.117) have the TRD (Re depleted age) of 1.1 Ga (USTC) and 1.4 Ga (CRPG), mid-Proterozoic. The Os isotope model age shows that the peridotite xenoliths from Cenozoic alkali basalt in Jiangsu-Anhui provinces have an old formation age (early- to mid- Proterozoic). They are not newly produced mantle after the Phanerozoic replacement of the lithosphere mantle, but residual fractions of Proterozoic mantle.     

Behavior of Re and Os during low-temperature alteration: Results from Himalayan soils and altered black shales

Re-Os analyses were performed on five soil profiles developed on silicate lithologies in the Narayani drainage basin of the Himalayas, as well as on several altered black shales and associated alteration phases. The results indicate that all of these samples have lost large amounts of Re. This Re loss approached 100% in the black shale-derived soils, which also most probably lost substantial quantities of Os. The near constancy of Os and Re concentrations with depth indicates that this loss occurred quite early in the alteration process, rather than progressively during the course of soil development. A slight decrease in ¹⁸⁷Os/¹⁸⁸Os was observed toward the surface of the two black shale soil profiles, possibly indicating a minor preferential mobility of radiogenic ¹⁸⁷Os for this lithology. In the black shale-derived saprolite and soils, the loss of Re and Os was related to the loss of organic carbon. The importance of this phase is underscored by the fact that organic material separated from a black shale sample accounted for nearly all of the Os contained in the whole rock. Analysis of alteration phases from the surface of a weathered black shale showed that Os liberated during alteration was partially reprecipitated in Fe oxides, with Os isotopic compositions very similar to that of the original rock, whereas Re was removed with the fluid phase.These results demonstrate the disproportionately large role that black shale weathering may play in determining the Re and Os contents of continental runoff and, thus, ultimately of seawater, but they also emphasize the possible complexity of this process. The data suggest that a large fraction of the Os contained in black shales is released during chemical alteration, which is apparently not the case for most other silicate rocks. Therefore, the potential contribution of black shales to the dissolved Os budget of runoff and river water may be even greater than that expected from the high Os concentrations of these rocks. The extent to which this Os will affect the seawater Os composition depends on how efficiently it is recaptured by secondary phases such as Fe-Mn oxides in situ or during transport. These results also underscore the high mobility of Re with respect to Os at every stage in the erosional process, thus explaining the order of magnitude increase in Re/Os ratio from the black shale source rocks to seawater.